208930

Tin(IV) chloride

98%

Manufacturer: Sigma Aldrich

CAS Number: 7646-78-8

Synonym(S): Stannic chloride fuming

Select a Size

Pack Size SKU Availability Price
250 G 208930-250-G In Stock ₹ 3,658.85
2 KG 208930-2-KG In Stock ₹ 13,574.55

208930 - 250 G

₹ 3,658.85

In Stock

Quantity

1

Base Price: ₹ 3,658.85

GST (18%): ₹ 658.593

Total Price: ₹ 4,317.443

vapor density

9 (vs air)

Quality Level

200

vapor pressure

10 mmHg ( 10 °C)18.6 mmHg ( 20 °C)20 mmHg ( 22 °C)

Assay

98%

form

liquid

reaction suitability

core: tinreagent type: Lewis acidreagent type: catalyst

bp

114 °C (lit.)

mp

−33 °C (lit.)

density

2.226 g/mL at 25 °C (lit.)

SMILES string

Cl[Sn](Cl)(Cl)Cl

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Description

  • General description: Stannic chloride (SnCl4) is a strong Lewis acid widely used as a promoter or catalyst in organic synthesis. It is soluble in most organic solvents.[1]
  • Application: Stannic chloride can be used to catalyze:Cyclization of trans β-monocyclohomofarnesic acid to form norambreinolide.[2]Formation of C-glycosides of aromatic compounds such as thiophene, naphthalene and phloroglucinol trimethyl ether.[3]Formal [4+2] cycloaddition of 3-ethoxycyclobutanones and allyltrialkylsilanes to form 3-ethoxy-5-[(trialkylsilyl)methyl]cyclohexan-1-ones.[4]Diastereoselective reaction of δ-alkoxyallylstannanes with aldehydes to form 1,5-diol derivatives.[5]Other applications of SnCl4:The SnCl4-2,6-dialkoxyphenols complexes can catalyze cyclization of poylenes, such as 4-(homogeranyl)toluene to form trans-fused tricyclic compound.[6]SnCl4 can act as a promoter during the reaction of ortho-aminobenzonitriles with β-ketoesters and β-enaminonitriles to form 4-aminoquinolines and 4-aminopyridines, respectively.[7]SnCl4-silver perchlorate forms an effective catalytic system for the stereoselective of glycosylation 1-O-acetyl glucose.[8]

SAFETY INFORMATION

Pictograms

GHS05,GHS07

Signal Word

Danger

Hazard Statements

H314,H335,H412

Precautionary Statements

P261 - P271 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves