310700

Manganese(IV) oxide

Manufacturer: Sigma Aldrich

CAS Number: 1313-13-9

Synonym(S): Manganese dioxide

Select a Size

Pack Size SKU Availability Price
500 G 310700-500-G In Stock ₹ 5,228.48
2.5 KG 310700-2.5-KG In Stock ₹ 11,270.00

310700 - 500 G

₹ 5,228.48

In Stock

Quantity

1

Base Price: ₹ 5,228.48

GST (18%): ₹ 941.126

Total Price: ₹ 6,169.606

grade

reagent grade

Quality Level

200

Assay

≥90%

form

powder

particle size

10 μm

mp

535 °C (dec.) (lit.)

SMILES string

O=[Mn]=O

InChI

1S/Mn.2O

InChI key

NUJOXMJBOLGQSY-UHFFFAOYSA-N

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Description

  • General description: Manganese(IV) oxide is an oxidizing reagent that can be used for the oxidation of propargylic alcohols, benzylic or heterocyclic alcohols, saturated alcohols, 1,2-diols, allylic alcohols to α, β-ethylenic aldehydes or ketones, and amines to aldehydes, imines, amides, and diazo compounds. It can also be used for the conversion of allylic alcohols to α, β-ethylenic esters or amides, hydration of nitriles to amides, dehydrogenation and aromatization reactions[1].
  • Application: High-oxidation-state 3d metal complexes: Explores the catalytic properties of manganese(IV) oxide within high-oxidation-state complexes for advanced organic synthesis, demonstrating its critical role in accelerating chemical reactions and enhancing yield efficiencies, beneficial for pharmaceutical and chemical industries (Cheng J et al., 2018). Synthesis and properties of manganese complexes: Details the synthesis of new manganese complexes that demonstrate unique redox properties, useful for understanding electron transfer processes in various chemical and environmental contexts (Baffert C et al., 2002).

SAFETY INFORMATION

Pictograms

GHS08,GHS07

Signal Word

Warning

Hazard Statements

H302 + H332,H373

Precautionary Statements

P260 - P264 - P271 - P301 + P312 - P304 + P340 + P312 - P314

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - STOT RE 2 Inhalation

Target Organs

Brain

WGK

WGK 2

Flash Point(F)

does not flash

Flash Point(C)

does not flash