123579

Benzenesulfinic acid sodium salt

98%

Manufacturer: Sigma Aldrich

CAS Number: 873-55-2

Synonym(S): Sodium benzenesulfinate

Select a Size

Pack Size SKU Availability Price
25 G 123579-25-G In Stock ₹ 2,316.55
100 G 123579-100-G In Stock ₹ 4,719.70
500 G 123579-500-G In Stock ₹ 16,681.33

123579 - 25 G

₹ 2,316.55

In Stock

Quantity

1

Base Price: ₹ 2,316.55

GST (18%): ₹ 416.979

Total Price: ₹ 2,733.529

Quality Level

100

Assay

98%

form

solid

mp

>300 °C (lit.)

SMILES string

[Na+].[O-]S(=O)c1ccccc1

InChI

1S/C6H6O2S.Na/c7-9(8)6-4-2-1-3-5-6;/h1-5H,(H,7,8);/q;+1/p-1

InChI key

CHLCPTJLUJHDBO-UHFFFAOYSA-M

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Description

  • General description: Benzenesulfinic acid sodium salt when treated with alkynylselenonium salts yields (Z)-β-alkoxyvinylsulfones[1]. It undergoes rhodium-catalyzed desulfinative coupling with aldehydes to yield ketones[2].
  • Application: Benzenesulfinic acid sodium salt has been used in synthesis of sulfones by reaction of organic halides and sodium benzenesulfinate using higher alcohols or diols as solvents[3].It was also used in the synthesis of aryl sulfones via copper-catalyzed cross-coupling with boronic acids[4] and vinyl sulfones via reaction with vicinal dibromides[5].

SAFETY INFORMATION

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves