05512

(S)-(−)-1-Phenylethanol

≥98.5% (sum of enantiomers, GC)

Manufacturer: Sigma Aldrich

CAS Number: 1445-91-6

Synonym(S): (−)-Methyl phenyl carbinol, (S)-(−)-α-Methylbenzyl alcohol, (S)-(−)-sec-Phenylethyl alcohol

Select a Size

Pack Size SKU Availability Price
5 G 05512-5-G In Stock ₹ 20,047.90

05512 - 5 G

₹ 20,047.90

In Stock

Quantity

1

Base Price: ₹ 20,047.90

GST (18%): ₹ 3,608.622

Total Price: ₹ 23,656.522

Quality Level

100

Assay

≥98.5% (sum of enantiomers, GC)

form

liquid

optical activity

[α]/D −45±2°, c = 5% in methanol

optical purity

enantiomeric ratio: ≥97:3 (GC)

refractive index

n20/D 1.527

bp

88-89 °C/10 mmHg (lit.)

mp

9-11 °C (lit.)

density

1.012 g/mL at 20 °C (lit.)

SMILES string

C[C@H](O)c1ccccc1

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Description

  • General description: (S)-(-)-1-Phenylethanol can be prepared from acetophenone via enantioselective bioreduction in the presence of Rhizopus arrhizus as a biocatalyst.[1]
  • Application: (S)-(-)-1-Phenylethanol can be used as: A starting material to prepare (1S,3R,4S)-1-methyl-3,4-diphenyl-3,4-dihydro-1H-isochromene-3,4-diol (a cyclic hemiacetal) by reacting with benzil via dilithiation reaction.[2] A chiral solvent in the symmetric synthesis of substituted spiroundecenetriones via amino acid-catalyzed domino Knoevenagel/Diels-Alder reactions.[3]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319

Precautionary Statements

P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P332 + P313

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves