246956

(S)-(−)-1,1′-Bi(2-naphthol)

99%

Manufacturer: Sigma Aldrich

CAS Number: 18531-99-2

Synonym(S): (−)-2,2′-Dihydroxy-1,1′-dinaphthyl, (S)-(−)-1,1′-Binaphthalene-2,2′-diol, (S)-BINOL

Select a Size

Pack Size SKU Availability Price
1 G 246956-1-G In Stock ₹ 5,347.55
5 G 246956-5-G In Stock ₹ 6,278.50
25 G 246956-25-G In Stock ₹ 7,826.48

246956 - 1 G

₹ 5,347.55

In Stock

Quantity

1

Base Price: ₹ 5,347.55

GST (18%): ₹ 962.559

Total Price: ₹ 6,310.109

Quality Level

100

Assay

99%

optical activity

[α]22/D −34°, c = 1 in THF

optical purity

ee: 99% (HPLC)

mp

208-210 °C (lit.)

SMILES string

Oc1ccc2ccccc2c1-c3c(O)ccc4ccccc34

InChI

1S/C20H14O2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,21-22H

InChI key

PPTXVXKCQZKFBN-UHFFFAOYSA-N

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Description

  • Application: (S)-BINOL ligand in combination with titanium(IV) isopropoxide, forms (S)-(-)-BINOL-Ti complex, which is an effective chiral catalyst for:asymmetric addition of alkynylzinc to unactivated ketones[1]enantioselective ring-opening reaction of meso-stilbene oxide and cyclohexene oxide with anilines[2]asymmetric aryl transfers from triaryl(tetrahydrofuran)aluminum reagents to a wide variety of ketones[3]It can also react with zirconium(IV) isopropoxide isopropanol complex to form a chiral Lewis acid catalyst for the facile enantioselective allylation of aldehydes by allyltributyltin.[4]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319

Precautionary Statements

P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves