302473

Chlorobis(cyclooctene)rhodium(I),dimer

98%

Manufacturer: Sigma Aldrich

CAS Number: 12279-09-3

Synonym(S): [Rh(coe)2Cl]2

Select a Size

Pack Size SKU Availability Price
250 MG 302473-250-MG In Stock ₹ 20,468.40
1 G 302473-1-G In Stock ₹ 61,693.80

302473 - 250 MG

₹ 20,468.40

In Stock

Quantity

1

Base Price: ₹ 20,468.40

GST (18%): ₹ 3,684.312

Total Price: ₹ 24,152.712

Quality Level

100

Assay

98%

form

powder

reaction suitability

core: rhodiumreagent type: catalyst

mp

190 °C (dec.) (lit.)

SMILES string

Cl[Rh].Cl[Rh].C1CCCC=CCC1.C2CCCC=CCC2.C3CCCC=CCC3.C4CCCC=CCC4

InChI

1S/4C8H14.2ClH.2Rh/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;

InChI key

GQPAPAIPOLEZHT-XFCUKONHSA-L

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Description

  • Application: Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst: To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.[1]In direct C-arylation of N-unprotected indoles and pyrroles.[2] In the carboxylation of arenes via C-H bond activation.[3]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332,H315,H319,H335

Precautionary Statements

P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves