157929

Methyl (triphenylphosphoranylidene)acetate

98%

Manufacturer: Sigma Aldrich

CAS Number: 2605-67-6

Synonym(S): (Carbomethoxymethylene)triphenylphosphorane, (Methoxycarbonylmethylene)triphenylphosphorane

Select a Size

Pack Size SKU Availability Price
5 G 157929-5-G In Stock ₹ 1,840.25
25 G 157929-25-G In Stock ₹ 7,588.33
100 G 157929-100-G In Stock ₹ 26,131.55

157929 - 5 G

₹ 1,840.25

In Stock

Quantity

1

Base Price: ₹ 1,840.25

GST (18%): ₹ 331.245

Total Price: ₹ 2,171.495

Quality Level

200

Assay

98%

form

powder

reaction suitability

reaction type: C-C Bond Formation

mp

168-172 °C (lit.)

SMILES string

COC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C21H19O2P/c1-23-21(22)17-24(18-11-5-2-6-12-18,19-13-7-3-8-14-19)20-15-9-4-10-16-20/h2-17H,1H3

InChI key

NTNUDYROPUKXNA-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
Sigma Aldrich Fine Chemicals Biosciences Methyl (triphenylphosphoranylidene)acetate 98% | 2605-67-6 | MFCD00008455 | 5G
-- ₹ 6,981.70
Methyl 2-(triphenylphosphoranylidene)acetate
-- ₹ 855.60 - ₹ 8,641.56
2605-67-6 | Methyl (triphenylphosphoranylidene)acetate
-- ₹ 427.80 - ₹ 8,641.56

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Description

  • Application: Wittig reagent for the two-carbon homologation of aldehydes to α,β-unsaturated esters.[1] Also used in an efficient synthesis of pyrazoles via reaction with methyl diazoacetate in the presence of triethylamine.[2]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves