Description

• Application: Methylboronic acid can be used as a reagent:In the palladium-catalyzed Stille and Suzuki-Miyaura cross-couplings.[1][2]In the microwave-heated heterogeneous palladium (Pd)-catalytized reactions.[3]In ruthenium (Ru)-catalyzed silylation reactions[4]To prepare bis(aminotropone) titanium (Ti) catalysts for ethylene polymerizations.[5]In the enantioselective asymmetric bromoaminocyclization and bromoaminocyclization using amino-thiocarbamate catalysts.[6][7]To prepare common building blocks for pharmaceuticals and agrochemicals.[8]To prepare chrysin analogs by Suzuki-Miyaura coupling reactions.[9]To prepare casein kinase I inhibitors.[10]In the divergent C-H functionalizations directed by sulfonamide pharmacophores in drug discovery.[2]In the synthesis of unsymmetrical monosulfides from disulfides via copper-catalyzed coupling with boronic acids.[11]In a palladium-catalyzed coupling with enol tosylates.[12]For derivatizing many carbohydrates and biologically active compounds for GLC analysis.