196193

Red-Al® sodium bis(2-methoxyethoxy)aluminum hydride solution

≥60 wt. % in toluene

Manufacturer: Sigma Aldrich

CAS Number: 22722-98-1

Synonym(S): SBAH, Sodium bis(2-methoxyethoxy)aluminum dihydride, Sodium dihydrido-bis(2-methoxyethoxy)aluminate

Select a Size

Pack Size SKU Availability Price
50 G 196193-50-G In Stock ₹ 3,074.30
250 G 196193-250-G In Stock ₹ 10,392.00
500 G 196193-500-G In Stock ₹ 20,091.20

196193 - 50 G

₹ 3,074.30

In Stock

Quantity

1

Base Price: ₹ 3,074.30

GST (18%): ₹ 553.374

Total Price: ₹ 3,627.674

vapor pressure

21 mmHg ( 20 °C)

Quality Level

200

expl. lim.

7 %

reaction suitability

reagent type: reductant

concentration

≥60 wt. % in toluene

density

1.036 g/mL at 25 °C

SMILES string

[Na+].[H][Al-]([H])(OCCOC)OCCOC

InChI

1S/2C3H7O2.Al.Na.2H/c2*1-5-3-2-4;;;;/h2*2-3H2,1H3;;;;/q2*-1;2*+1;;

InChI key

XJIQVZMZXHEYOY-UHFFFAOYSA-N

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Description

  • General description: Red-Al® sodium bis(2-methoxyethoxy)aluminum hydride [NaAlH2(OCH2CH2OCH3)2] is used as a versatile reducing agent in organic synthesis. It is used to reduce: Aldehydes, ketones, esters, and anhydrides to primary alcohols. Ketoximes and aldoximes to primary amines. Cyclic compounds such as lactones and epoxides to diols.It is also used as a catalyst in the ring-opening polymerization reactions.[1][2][3]SBAH is a reducing agent used to reduce functional groups like carbonyls, amides, epoxides, esters, and carboxylic acids.[4]
  • Application: Employed in the efficient reduction of N-Boc amino acid secondary amides leading to chiral diamines.[5]
  • Legal Information: Red-Al is a registered trademark of Merck KGaA, Darmstadt, Germany

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H260,H304,H314,H336,H361d,H373,H412

Precautionary Statements

P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3 - Water-react 1

Target Organs

Central nervous system

Supplementary Hazards

EUH014

WGK

WGK 3

Flash Point(F)

39.2 °F

Flash Point(C)

4 °C