274259

Methyl P,P-bis(2,2,2-trifluoroethyl)phosphonoacetate

95%

Manufacturer: Sigma Aldrich

CAS Number: 88738-78-7

Synonym(S): Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate

Select a Size

Pack Size SKU Availability Price
5 G 274259-5-G In Stock ₹ 16,360.00

274259 - 5 G

₹ 16,360.00

In Stock

Quantity

1

Base Price: ₹ 16,360.00

GST (18%): ₹ 2,944.80

Total Price: ₹ 19,304.80

Assay

95%

form

liquid

reaction suitability

reaction type: C-C Bond Formation

refractive index

n20/D 1.370 (lit.)

density

1.504 g/mL at 25 °C (lit.)

SMILES string

COC(=O)CP(=O)(OCC(F)(F)F)OCC(F)(F)F

InChI

1S/C7H9F6O5P/c1-16-5(14)2-19(15,17-3-6(8,9)10)18-4-7(11,12)13/h2-4H2,1H3

InChI key

PVSJXEDBEXYLML-UHFFFAOYSA-N

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Description

  • Application: Methyl P,P-bis(2,2,2-trifluoroethyl)phosphonoacetate can be used:In one of the key synthetic steps for the preparation of trans-hydrindanes and (R)-(+)-umbelactone.[1][2]To prepare a cis-olefinic ester derivative by Still–Gennari olefination of an aldehyde derivative using 18-crown ether and potassium bis(trimethylsilyl)amide (KHMDS).[3]In the synthesis of (−)-(6S,2′S)-epi cryptocaryalactone.[4]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves