296813

Sodium cyanoborohydride solution

1.0 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 25895-60-7

Synonym(S): Sodium borocyanohydride, Sodium cyanoborohydride, Sodium cyanotrihydroborate

Select a Size

Pack Size SKU Availability Price
100 ML 296813-100-ML In Stock ₹ 10,781.70

296813 - 100 ML

₹ 10,781.70

In Stock

Quantity

1

Base Price: ₹ 10,781.70

GST (18%): ₹ 1,940.706

Total Price: ₹ 12,722.406

Quality Level

200

reaction suitability

reagent type: reductant

concentration

1.0 M in THF

solubility

THF: soluble(lit.)alcohol: soluble(lit.)hydrocarbons: insoluble(lit.)water: soluble(lit.)

density

0.915 g/mL at 25 °C

SMILES string

[Na+].[H][B-]([H])([H])C#N

InChI

1S/CH3BN.Na/c2-1-3;/h2H3;/q-1;+1

InChI key

CVDUGUOQTVTBJH-UHFFFAOYSA-N

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Description

  • General description: Sodium cyanoborohydride is a versatile reducing agent stable in aqueous solution at pH 7.2.[1] It is a weaker reducing agent as compared to NaBH4. It effectively reduces Schiff bases.[2] NaCNBH4 participates in the reductive methylation for the efficient and selective conversion of the e-amino groups of lysyl residues in proteins to the mono- and dimethyl derivatives.[2]
  • Application: Reactant for:Direct conversion of heterocyclic aldehydes to esters (oxidizing behavior)Reductive amination reactionsIntramolecular reductive cyclization reactionsReductions reactionsPreparation of dicyanoborate-based ionic liquids as hypergolic fluids for bipropellants

SAFETY INFORMATION

Pictograms

GHS02,GHS06,GHS08,GHS05,GHS09

Signal Word

Danger

Hazard Statements

H225,H260,H301 + H311 + H331,H314,H335,H336,H351,H410

Precautionary Statements

P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 3

Flash Point(F)

-4.0 °F

Flash Point(C)

-20 °C