316393

Sodium triacetoxyborohydride

97%

Manufacturer: Sigma Aldrich

CAS Number: 56553-60-7

Synonym(S): STAB

Select a Size

Pack Size SKU Availability Price
25 G 316393-25-G In Stock ₹ 3,850.00
100 G 316393-100-G In Stock ₹ 14,610.00
500 G 316393-500-G In Stock ₹ 54,698.73
1 KG 316393-1-KG In Stock ₹ 62,840.00

316393 - 25 G

₹ 3,850.00

In Stock

Quantity

1

Base Price: ₹ 3,850.00

GST (18%): ₹ 693.00

Total Price: ₹ 4,543.00

Quality Level

200

Assay

97%

reaction suitability

reagent type: reductant

mp

116-120 °C (dec.) (lit.)

SMILES string

[Na+].CC(=O)O[BH-](OC(C)=O)OC(C)=O

InChI

1S/C6H10BO6.Na/c1-4(8)11-7(12-5(2)9)13-6(3)10;/h7H,1-3H3;/q-1;+1

InChI key

HHYFEYBWNZJVFQ-UHFFFAOYSA-N

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Description

  • General description: Sodium triacetoxyborohydride (NaBH(OAc)3) is particularly effective in reductive aminations due to its large scope, mildness, and selectivity.[1] It is preferred to sodium cyanoborohydride(NaBH3CN) in many applications due to reduced toxicity of the side products formed, and better yields and reproducibility during synthesis.
  • Application: Sodium triacetoxyborohydride or [NaBH(OAc)3] can be used as a reagent: In the reductive amination of ketones and aldehydes.[2][3] To prepare N-benzyl-γ-valerolactam by reacting with methyl 4-oxopentanoate and benzylamine via reductive amination/lactamization.[3] To reduce imines and enamines to corresponding amines.[2] To reduce quinolines and isoquinolines to corresponding tetrahydro derivatives.[2] In the hydroboration of alkenes.[4] To synthesize nitroxide biradicals for creating high relaxivity terminal groups linkage to dendrimers.[5]Applications using Sodium triacetoxyborohydride

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H228,H260,H302,H318,H360FD

Precautionary Statements

P210 - P231 + P232 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Sol. 1 - Repr. 1B - Water-react 1

Supplementary Hazards

EUH014

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable