345113

Di-n-butylmagnesium solution

1.0 M in heptane

Manufacturer: Sigma Aldrich

CAS Number: 1191-47-5

Synonym(S): Bis-n-butylmagnesium, Dibutylmagnesium

Select a Size

Pack Size SKU Availability Price
100 ML 345113-100-ML In Stock ₹ 7,523.38
800 ML 345113-800-ML In Stock ₹ 18,510.75

345113 - 100 ML

₹ 7,523.38

In Stock

Quantity

1

Base Price: ₹ 7,523.38

GST (18%): ₹ 1,354.208

Total Price: ₹ 8,877.588

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in heptane

density

0.713 g/mL at 25 °C

SMILES string

CCCC[Mg]CCCC

InChI

1S/2C4H9.Mg/c2*1-3-4-2;/h2*1,3-4H2,2H3;

InChI key

ODHFJIDDBSDWNU-UHFFFAOYSA-N

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Description

  • General description: Di-n-butylmagnesium solution is a useful reagent for the synthesis of organomagnesium compounds.
  • Application: Di-n-butylmagnesium solution can be used as a reagent for the deprotection of aromatic and aliphatic benzyl thioethers to synthesize corresponding benzylthiols in the presence of titanocene dichloride[1]. It can also be used as a catalyst to synthesize enantioenriched nitrogen-containing heterocyclic derivatives by the asymmetric ring-opening reaction of aziridines with substituted tetrazoles in the presence of chiral ligand[2].

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07,GHS09

Signal Word

Danger

Hazard Statements

H225,H250,H260,H304,H314,H336,H410

Precautionary Statements

P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system

Supplementary Hazards

EUH014

WGK

WGK 2

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves