392715

N-Fluorobenzenesulfonimide

97%

Manufacturer: Sigma Aldrich

CAS Number: 133745-75-2

Synonym(S): N-Fluorodi(benzenesulfonyl)amine, N-Fluorodibenzenesulfonimide, NFSI

Select a Size

Pack Size SKU Availability Price
5 G 392715-5-G In Stock ₹ 7,079.55

392715 - 5 G

₹ 7,079.55

In Stock

Quantity

1

Base Price: ₹ 7,079.55

GST (18%): ₹ 1,274.319

Total Price: ₹ 8,353.869

Quality Level

100

Assay

97%

form

powder

mp

110 °C (dec.) (lit.)

SMILES string

FN(S(=O)(=O)c1ccccc1)S(=O)(=O)c2ccccc2

InChI

1S/C12H10FNO4S2/c13-14(19(15,16)11-7-3-1-4-8-11)20(17,18)12-9-5-2-6-10-12/h1-10H

InChI key

RLKHFSNWQCZBDC-UHFFFAOYSA-N

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Description

  • General description: N-Fluorobenzenesulfonimide (NFSi) is a commonly used electrophilic fluorinating agent in organic synthesis to introduce fluorine into neutral organic molecules. It is also used to fluorinate nucleophilic substrates such as reactive organometallic species and malonate anions.[1][2]NFSi can be synthesized by the reaction of benzenesulfonimide with fluorine.[1]
  • Application: Reagent employed in a palladium-catalyzed enantioselective fluorination of t-butoxycarbonyl lactones and lactams.[3] Also used in the electrophilic difluorination of dihalopyridines with butyl lithium[4] and in the direct conversion of alcohols to dibenzenesulfonamides with triphenylphosphine.[5]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves