658235

Lithium dimethylaminoborohydride solution

1 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 53042-33-4

Synonym(S): N-Methylmethanamine boron complex, Lithium (dimethylamino)trihydroborate, Lithium trihydro(N-methylmethanaminato)borate

Select a Size

Pack Size SKU Availability Price
100 ML 658235-100-ML In Stock ₹ 15,730.00

658235 - 100 ML

₹ 15,730.00

In Stock

Quantity

1

Base Price: ₹ 15,730.00

GST (18%): ₹ 2,831.40

Total Price: ₹ 18,561.40

reaction suitability

reagent type: reductant

Quality Level

100

concentration

1 M in THF

refractive index

n20/D 1.423

density

0.882 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

[Li+].[BH3-]N(C)C

InChI

1S/C2H9BN.Li/c1-4(2)3;/h1-3H3;/q-1;+1

InChI key

CEDUMRZWZLVFKS-UHFFFAOYSA-N

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Description

  • General description: Lithium dimethylaminoborohydride is a reagent exhibiting dual properties like a metal hydride and nitrogen nucleophile. It is generally considered as an alternative to lithium aluminum hydride (LAH) for the reduction of carbonyl compounds, amides, and lactams.[1][2]
  • Application: Lithium Aminoborohydride (LAB) ReagentsReactant for:B-H oxidative addition reactionsReduction and amination reactionsReduction of N-alkyl lactamsSynthesis of tertiary amine-boranes

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS07

Signal Word

Danger

Hazard Statements

H225,H302,H319,H335,H351

Precautionary Statements

P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup