767840

Zinc difluoromethanesulfinate

95%

Manufacturer: Sigma Aldrich

CAS Number: 1355729-38-2

Synonym(S): Bis(((difluoromethyl)sulfinyl)oxy)zinc, 1,1-difluoro-methanesulfinic acid zinc salt (2:1), Baran difluoromethylation reagent, DFMS

Select a Size

Pack Size SKU Availability Price
1 G 767840-1-G In Stock ₹ 23,500.00
10 G 767840-10-G In Stock ₹ 1,40,107.98
100 G 767840-100-G In Stock ₹ 5,56,112.73

767840 - 1 G

₹ 23,500.00

In Stock

Quantity

1

Base Price: ₹ 23,500.00

GST (18%): ₹ 4,230.00

Total Price: ₹ 27,730.00

Quality Level

100

Assay

95%

form

solid

reaction suitability

reaction type: C-C Bond Formationreaction type: Fluorinationsreagent type: catalystreaction type: C-H Activationreagent type: diversification reagent

storage temp.

2-8°C

SMILES string

FC(F)S(=O)O[Zn]OS(=O)C(F)F

InChI

1S/2CH2F2O2S.Zn/c2*2-1(3)6(4)5;/h2*1H,(H,4,5);/q;;+2/p-2

InChI key

UGEYAPVLXKEKMP-UHFFFAOYSA-L

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Description

  • General description: Material is complexed with up to 1 equivalent of ZnCl2
  • Application: Zinc difluoromethanesulfinate (DFMS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.†Practical and Innate Carbon-Hydrogen Functionalization of HeterocyclesDFMS is a new reagent for direct difluoromethylation of organic substrates via a radical process. This mild, operationally simple, chemoselective, and scalable difluoromethylation method is compatible with a range of nitrogen-containing heteroarene substrates of varying complexity as well as select classes of conjugated p−systems and thiols.†A New Reagent for Direct DifluoromethylationLearn More at the Professor and Product Portal of Professor Phil S. Baran.
  • Linkage: Frequently Asked Questions are available for this Product.

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable