901251

[2,2′-Bipyridine]-6-carboxylic acid hydrochloride

Manufacturer: Sigma Aldrich

CAS Number: 4392-87-4

Synonym(S): PPA directing group

Select a Size

Pack Size SKU Availability Price
500 MG 901251-500-MG In Stock ₹ 14,289.00

901251 - 500 MG

₹ 14,289.00

In Stock

Quantity

1

Base Price: ₹ 14,289.00

GST (18%): ₹ 2,572.02

Total Price: ₹ 16,861.02

form

powder or crystals

Quality Level

100

reaction suitability

reaction type: C-C Bond Formationreagent type: catalystreagent type: ligandreaction type: C-H Activation

InChI

1S/C11H8N2O2/c14-11(15)10-6-3-5-9(13-10)8-4-1-2-7-12-8/h1-7H,(H,14,15)

InChI key

ZQTILGDVDYWICD-UHFFFAOYSA-N

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Description

  • Application: Developed in the Engle lab, this 2,2′-bipyridylamide (PPA) is a pincer-like, removable tridentate directing group that stabilizes 6-membered palladacycles for olefin functionalization. Together with similar ligand PAQ (901250), researchers demonstrated regioselective remote hydrocarbofunctionalization of alkene-containing substrate classes (e.g. 4-pentenoic acids, allylic alcohols, homoallyl amines, bis-homoallylamines) using Pd(II) catalysis.
  • Other Notes: Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable