902489
Tris(trimethylsilyl)silanol
≥95%
Manufacturer: Sigma Aldrich
CAS Number: 7428-60-6
Synonym(S): (Hydroxy-bis(trimethylsilyl)silyl)-trimethylsilane, (TMS)3SiOH, 1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)trisilan-2-ol, Supersilanol
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 902489-1-G | In Stock | ₹ 21,411.85 |
| 5 G | 902489-5-G | In Stock | ₹ 67,764.50 |
902489 - 1 G
In Stock
Quantity
1
Base Price: ₹ 21,411.85
GST (18%): ₹ 3,854.133
Total Price: ₹ 25,265.983
Assay
≥95%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
refractive index
n/D 1.496
density
0.859 g/mL
InChI
1S/C9H28OSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h10H,1-9H3
InChI key
ABTWCNHNRLMBFR-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Hydroxy-tris(trimethylsilyl)silane | -- | ₹ 10,352.76 | |
| | 7428-60-6 | 2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- | -- | ₹ 7,529.28 |
Related Products
Description
- Application: Under a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with dMesSCF3 (901466) and Ir photocatalyst (902217 or 902225).
- Other Notes: A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
200.3 °F
Flash Point(C)
93.5 °C