91741

Trimethylsilyl trifluoromethanesulfonate

purum, ≥98.0% (T)

Manufacturer: Sigma Aldrich

CAS Number: 27607-77-8

Synonym(S): TMS triflate, TMSOTf, Trifluoromethanesulfonic acid trimethylsilylester

Select a Size

Pack Size SKU Availability Price
10 ML 91741-10-ML In Stock ₹ 5,196.00
50 ML 91741-50-ML In Stock ₹ 18,759.73
250 ML 91741-250-ML In Stock ₹ 56,712.18

91741 - 10 ML

₹ 5,196.00

In Stock

Quantity

1

Base Price: ₹ 5,196.00

GST (18%): ₹ 935.28

Total Price: ₹ 6,131.28

grade

purum

Quality Level

200

Assay

≥98.0% (T)

form

liquid

refractive index

n20/D 1.36 (lit.)

bp

77 °C/80 mmHg (lit.)

density

1.228 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)OS(=O)(=O)C(F)(F)F

InChI

1S/C4H9F3O3SSi/c1-12(2,3)10-11(8,9)4(5,6)7/h1-3H3

InChI key

FTVLMFQEYACZNP-UHFFFAOYSA-N

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Description

  • Application: Trimethylsilyl trifluoromethanesulfonate may be used to catalyze:Allylation of acetals to form homoallyl ethers.[1]Synthesis of 1,2-trans-glycosides.[2]Conversion of alcohols to esters.[3]Aminomethylation of silyl enol ethers with aminomethyl alkyl ethers.[4]Glycosidation of (+)-4-demethoxyanthracyclinones.[5]
  • Other Notes: Efficient silylating agent and strong Lewis acid catalyst [6][7]; Review [8]

SAFETY INFORMATION

Pictograms

GHS02,GHS05

Signal Word

Danger

Hazard Statements

H226,H314

Precautionary Statements

P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

Supplementary Hazards

EUH014

WGK

WGK 3

Flash Point(F)

77.0 °F

Flash Point(C)

25 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves