155071

Azidotrimethylsilane

95%

Manufacturer: Sigma Aldrich

CAS Number: 4648-54-8

Synonym(S): Trimethylsilyl azide

Select a Size

Pack Size SKU Availability Price
10 G 155071-10-G In Stock ₹ 8,833.20
50 G 155071-50-G In Stock ₹ 20,361.83

155071 - 10 G

₹ 8,833.20

In Stock

Quantity

1

Base Price: ₹ 8,833.20

GST (18%): ₹ 1,589.976

Total Price: ₹ 10,423.176

Quality Level

100

Assay

95%

form

liquid

refractive index

n20/D 1.414 (lit.)

bp

52-53 °C/175 mmHg (lit.)

density

0.868 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(C)N=[N+]=[N-]

InChI

1S/C3H9N3Si/c1-7(2,3)6-5-4/h1-3H3

InChI key

SEDZOYHHAIAQIW-UHFFFAOYSA-N

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Description

  • General description: Azidotrimethylsilane (TMSN3) is a a colorless and stable organosilane reagent. It shows very slow decomposition at high temperatures. It is a very commonly used azide source and has been used in the synthesis of aminotriazole ligands. Azidotrimethylsilane can be easily synthesised by adding chlorotrimethylsilane dropwise to a stirred solution of NaN3 in diethylene glycol dimethyl ether.[1]
  • Application: Azidotrimethylsilane can be used as:A nitrogen precursor to prepare GaN nanowire via metal-organic chemical vapor deposition method.An electrolyte additive in Li-O2 batteries. The addition of TMSN3 results in the formation of robust solid electrolyte interphase.An efficient reagent in the synthesis of tetrazoles, fullerenyl azide, and α-azido oximes.A silylating agent in the O-trimethyl silylation of alcohols and phenols.

SAFETY INFORMATION

Pictograms

GHS02,GHS06

Signal Word

Danger

Hazard Statements

H225,H301 + H311 + H331

Precautionary Statements

P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves