254363

Methylmagnesium iodide solution

3.0 M in diethyl ether

Manufacturer: Sigma Aldrich

CAS Number: 917-64-6

Synonym(S): Iodomethylmagnesium, Methylmagnesium iodine

Select a Size

Pack Size SKU Availability Price
100 ML 254363-100-ML In Stock ₹ 10,511.08
800 ML 254363-800-ML In Stock ₹ 39,543.73

254363 - 100 ML

₹ 10,511.08

In Stock

Quantity

1

Base Price: ₹ 10,511.08

GST (18%): ₹ 1,891.994

Total Price: ₹ 12,403.074

Quality Level

200

reaction suitability

reaction type: Grignard Reaction

concentration

3.0 M in diethyl ether

density

1.261 g/mL at 25 °C

SMILES string

C[Mg]I

InChI

1S/CH3.HI.Mg/h1H3;1H;/q;;+1/p-1

InChI key

AUPXBVDHVRZMIB-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
Sigma Aldrich Fine Chemicals Biosciences Methylmagnesium iodide solution 3.0 M in diethyl ether | 917-64-6 | MFCD00001026 | 100ML
-- ₹ 9,632.34
Methylmagnesium iodide solution
-- ₹ 10,511.08 - ₹ 39,543.73
917-64-6 | Methylmagnesium iodide
-- ₹ 81,795.36

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Description

  • Application: Methylmagnesium iodide solution can be used: To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.[1] In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.[2] To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.[3] In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.[4]

SAFETY INFORMATION

Pictograms

GHS02,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H224,H260,H314,H336

Precautionary Statements

P210 - P231 + P232 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P403 + P233

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves