702757

Potassium tert-pentoxide solution

2 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 41233-93-6

Synonym(S): Potassium tert-amylate, Potassium (2-methyl-2-butoxide), Potassium tert-pentylate

Select a Size

Pack Size SKU Availability Price
100 ML 702757-100-ML In Stock ₹ 19,246.85
500 ML 702757-500-ML In Stock ₹ 73,674.95

702757 - 100 ML

₹ 19,246.85

In Stock

Quantity

1

Base Price: ₹ 19,246.85

GST (18%): ₹ 3,464.433

Total Price: ₹ 22,711.283

form

liquid

Quality Level

100

concentration

2 M in THF

density

0.920 g/mL at 25 °C

SMILES string

[K+].CCC(C)(C)[O-]

InChI

1S/C5H11O.K/c1-4-5(2,3)6;/h4H2,1-3H3;/q-1;+1

InChI key

ZRLVQFQTCMUIRM-UHFFFAOYSA-N

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Description

  • General description: Potassiumtert-pentoxide solution is a strong and sterically hindered alkoxide baseprepared by treating oil-free potassium hydride with anhydrous t-pentylalcohol in anhydrous solvent.
  • Application: Potassium tert-pentoxide solution can be used as a base in the:Wittig reaction of ketoesters with methyltriphenylphosphonium bromide to synthesize alkenes.Palladium-catalyzed Buchwald-Hartwig amination reaction.It can also be used:To prepare potassium tert-pentoxide-crown ether complexes, which is used as a Lewis base catalyst in Mukaiyama aldol reaction.As an activator for (difluoromethyl)trimethylsilane to generate difluoromethyl-carbanion which reacts with isothiocyanate to synthesize α, α-difluoromethyl thioamide.
  • Features and Benefits: In the absence of air and moisture, potassium tert-pentoxide solutions in benzene or toluene may be stored in a refrigerator for up to 1 year without significant deterioration.

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H302,H314,H335,H336,H351

Precautionary Statements

P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 3

Flash Point(F)

1.4 °F

Flash Point(C)

-17 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves