192120

Borane dimethyl sulfide complex solution

2.0 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 13292-87-0

Synonym(S): BMS, Trihydro[thiobis[methane]]boron

Select a Size

Pack Size SKU Availability Price
100 ML 192120-100-ML In Stock ₹ 6,960.48
800 ML 192120-800-ML In Stock ₹ 36,610.15

192120 - 100 ML

₹ 6,960.48

In Stock

Quantity

1

Base Price: ₹ 6,960.48

GST (18%): ₹ 1,252.886

Total Price: ₹ 8,213.366

form

liquid

Quality Level

200

reaction suitability

reagent type: reductant

concentration

2.0 M in THF

density

0.855 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

InChI key

RMHDLBZYPISZOI-UHFFFAOYSA-N

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Description

  • General description: Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters.[1] Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.[2]
  • Application: Borane dimethyl sulfide complex (BMS) solution may be used in the following studies:One-pot conversion of alkynes into 1,2-diols.[3]Preparation of iminopentitols.[4] Reduction of representative organic functional groups, such as esters, nitriles and amides.[5] Used along with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.[6] Asymmetric reduction of ferrocenyl-1,3-diketones to chiral 1,3-diols.[7] Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.[8]

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H260,H302 + H312,H318,H335,H336,H351,H360FD

Precautionary Statements

P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - STOT SE 3 - Water-react 1

Target Organs

Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 1

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves