227439

Lawesson reagent

97%

Manufacturer: Sigma Aldrich

CAS Number: 19172-47-5

Synonym(S): 2,4-Bis(4-methoxyphenyl)-2,4-dithioxo-1,3,2,4-dithiadiphosphetane, 2,4-Bis-(4-methoxyphenyl)-1,3-dithia-2,4-diphosphetane 2,4-disulfide, 4-Methoxyphenylthiophosphoric cyclic di(thioanhydride), LR

Select a Size

Pack Size SKU Availability Price
10 G 227439-10-G In Stock ₹ 2,305.73
25 G 227439-25-G In Stock ₹ 3,052.65
100 G 227439-100-G In Stock ₹ 9,796.63

227439 - 10 G

₹ 2,305.73

In Stock

Quantity

1

Base Price: ₹ 2,305.73

GST (18%): ₹ 415.031

Total Price: ₹ 2,720.761

Quality Level

100

Assay

97%

form

powder

mp

228-230 °C (lit.)

SMILES string

COc1ccc(cc1)P2(=S)SP(=S)(S2)c3ccc(OC)cc3

InChI

1S/C14H14O2P2S4/c1-15-11-3-7-13(8-4-11)17(19)21-18(20,22-17)14-9-5-12(16-2)6-10-14/h3-10H,1-2H3

InChI key

CFHGBZLNZZVTAY-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
eMolecules​ Lawesson's reagent | 19172-47-5 | MFCD00005171 | 25g
-- ₹ 4,255.75

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Description

  • General description: Lawesson′s reagent is generally used as a thiation agent in organic synthesis for the conversion of oxygen functionalities into their thio analogs. It facilitates the conversion of the carbonyl group to thiocarbonyl group as well as carbon-oxygen single bond into a carbon-sulfur single bond.[1][2][2]
  • Application: Lawesson reagent can be used as a reagent to synthesize:Oxthiaphosphinine-3-sulfide derivatives by the reaction with Mannich bases of β-naphthol and 8-hydroxyquinoline.[3]1,3,5,2-Trithiaphosphinane-2-sulfide derivatives by reacting with benzaldehyde in the presence of trialkyl phosphite.[3]2,4,6-Triphenyl-1,3,5-trithiane from benzaldehyde and ethyl acrylate.[3]9-Benzanthronethione by thionation of 9-benzanthone oxime.[2]1,2,4-Trithiolane from 2,2,4,4-tetramethyl-3-thioxocyclobutanone S-oxide.[4]Sulfur derivatives of triterpenic oxo compounds.[5]Tropothione in situ at room temperature and to trap it with dieneophiles.[6]

SAFETY INFORMATION

Pictograms

GHS02

Signal Word

Danger

Hazard Statements

H261

Precautionary Statements

P231 + P232 - P422

Hazard Classifications

Water-react 2

Supplementary Hazards

EUH029

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable