429007

1-Propynylmagnesium bromide solution

0.5 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 16466-97-0

Synonym(S): 1-Propyn-1-ylmagnesium bromide, Bromo(prop-1-yn-1-yl)magnesium, Bromo-1-propynylmagnesium

Select a Size

Pack Size SKU Availability Price
100 ML 429007-100-ML In Stock ₹ 14,910.00
800 ML 429007-800-ML In Stock ₹ 40,270.00

429007 - 100 ML

₹ 14,910.00

In Stock

Quantity

1

Base Price: ₹ 14,910.00

GST (18%): ₹ 2,683.80

Total Price: ₹ 17,593.80

Quality Level

200

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in THF

bp

65-67 °C

density

0.941 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC#C[Mg]Br

InChI

1S/C3H3.BrH.Mg/c1-3-2;;/h1H3;1H;/q;;+1/p-1

InChI key

YVJBCTFVENNIOV-UHFFFAOYSA-M

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Description

  • General description: 1-Propynylmagnesiumbromide solution is 1-propynylmagnesium bromide in 0.5M tetrahydrofuran.1-propynylmagnesium bromide solution used as a Grignard reagent in chemical synthesis. This research reagent can be used for chemical and organic transformations. It is used as a regent in the conversion of [11C]CO2 to [11C] amides via Mitsunobu reaction.[1][2]
  • Application: Preparation of hydroxy enynes which underwent gold(I)-catalyzed benzannulation leading to tetrahydronaphthalenes.[3]

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H261,H302,H314,H335,H336,H351

Precautionary Statements

P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves