Description

• Application: Reagent Used forReductive silylation and the preparation of trifluoro- and difluoromethylsilanes by reductive coupling of fluoromethyl sulfones, sulfoxides and sulfides with chlorosilanes[1]Fluoroalkylation/chloroalkylation of α,β-enones, arynes, acetylenic ketones and other Michael acceptors[2]Difluoromethylation of primary alkyl halides via nucleophilic substitution-reductive desulfonylation[3]Reagent used in Preparation ofα-difluoromethyl amines via stereoselective (phenylsulfonyl)difluoromethylation of chiral sulfinyl aldimines[4]Anti-difluoropropanediols via potassium tert-butoxide-catalyzed difluoromethylenation of aldehydes[5]β-difluoromethylated and β-difluoromethylenated alcohols and amines by regioselective nucleophilic difluoromethylation of 1,2-cyclic sulfates and sulfamidates[6]Difluoroalkenes from alkyl halides via nucleophilic substitution-elimination[7]Difluoromethyl alcohol derivatives from enolizable and non-enolizable carbonyl compounds using nucleophilic phenylsulfonyldifluoromethylation-reductive desulfonylation strategy[8]Fluoromethylated vicinal ethylenediamines via fluoromethylation of chiral α-aminobutanesulfinimines with (phenylsulfonyl)fluoromethanes followed by reductive desulfonylation and alcoholysis[9]