416665

tert-Butyl hydroperoxide solution

5.0-6.0 M in decane

Manufacturer: Sigma Aldrich

CAS Number: 75-91-2

Synonym(S): 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, TBHP

Select a Size

Pack Size SKU Availability Price
25 ML 416665-25-ML In Stock ₹ 2,013.45
100 ML 416665-100-ML In Stock ₹ 3,907.83

416665 - 25 ML

₹ 2,013.45

In Stock

Quantity

1

Base Price: ₹ 2,013.45

GST (18%): ₹ 362.421

Total Price: ₹ 2,375.871

form

liquid

Quality Level

200

reaction suitability

reagent type: oxidant

concentration

5.0-6.0 M in decane55.4-65.1% (Thiosulphate, titration)

impurities

<4% water

refractive index

n20/D 1.402

density

0.808 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

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Description

  • General description: tert-Butyl hydroperoxide is an organic peroxide, used in oxidation processes.
  • Application: tert-Butyl hydroperoxide may be used in:osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions[1] catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary[2]oxidation of dibenzothiophenes[3]

SAFETY INFORMATION

Pictograms

GHS02,GHS06,GHS08,GHS05,GHS09

Signal Word

Danger

Hazard Statements

H226,H242,H302,H304,H311,H314,H317,H330,H335,H341,H411

Precautionary Statements

P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

109.4 °F

Flash Point(C)

43 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves