72020

Sodium tetraphenylborate

puriss. p.a., ACS reagent, ≥99.5% (NT)

Manufacturer: Sigma Aldrich

CAS Number: 143-66-8

Synonym(S): Tetraphenylboron sodium

Select a Size

Pack Size SKU Availability Price
50 G 72020-50-G In Stock ₹ 21,108.75
250 G 72020-250-G In Stock ₹ 77,907.53

72020 - 50 G

₹ 21,108.75

In Stock

Quantity

1

Base Price: ₹ 21,108.75

GST (18%): ₹ 3,799.575

Total Price: ₹ 24,908.325

grade

ACS reagentpuriss. p.a.

Quality Level

200

Assay

≥99.5% (NT)

form

solid

loss

≤0.5% loss on drying, 110 °C

anion traces

chloride (Cl-): ≤50 mg/kgsulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤100 mg/kgCd: ≤5 mg/kgCo: ≤5 mg/kgCr: ≤5 mg/kgCu: ≤5 mg/kgFe: ≤5 mg/kgK: ≤500 mg/kgMg: ≤5 mg/kgMn: ≤5 mg/kgNi: ≤5 mg/kgPb: ≤5 mg/kgZn: ≤5 mg/kg

SMILES string

[Na+].c1ccc(cc1)[B-](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C24H20B.Na/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;/q-1;+1

InChI key

HFSRCEJMTLMDLI-UHFFFAOYSA-N

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Description

  • General description: Sodium tetraphenylborate (Ph4BNa) undergoes rhodium-catalyzed addition reactions with N-phenylsulfonyl aldimines to afford R(Ph)CHNHSO2Ph.[1]
  • Application: Sodium tetraphenylborate (Ph4BNa) may be used in the synthesis of polyfunctional biaryls via modified Suzuki cross-coupling reaction.[2] It may be employed as a derivatization reagent for the analysis of methylmercury and ethylmercury by gas chromatography (GC) coupled with atomic fluorescence spectrometry (AFS), microwave-induced plasma atomic emission spectrometry (AES) and mass spectrometry (MS).[3]
  • Other Notes: Reagent for the precipitation and titration of potassium[4][5]; For the amperometric titration of amines, quaternary ammonium compounds and potassium[6]; For the titration of quaternary ammonium surfactants[7]; Titrant for amines and NH4Cl in the presence of a K selective electrode[8]

SAFETY INFORMATION

Pictograms

GHS06

Signal Word

Danger

Hazard Statements

H301

Precautionary Statements

P264 - P270 - P301 + P310 - P405 - P501

Hazard Classifications

Acute Tox. 3 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves