735353

Lithium 2,2,6,6-tetramethylpiperidide

95%

Manufacturer: Sigma Aldrich

CAS Number: 38227-87-1

Synonym(S): 2,2,6,6-Tetramethylpiperidine lithium salt (1:1), LTMP

Select a Size

Pack Size SKU Availability Price
10 G 735353-10-G In Stock ₹ 15,858.63
25 G 735353-25-G In Stock ₹ 21,217.00

735353 - 10 G

₹ 15,858.63

In Stock

Quantity

1

Base Price: ₹ 15,858.63

GST (18%): ₹ 2,854.553

Total Price: ₹ 18,713.183

Quality Level

100

Assay

95%

form

solid

SMILES string

[Li]N1C(C)(C)CCCC1(C)C

InChI

1S/C9H18N.Li/c1-8(2)6-5-7-9(3,4)10-8;/h5-7H2,1-4H3;/q-1;+1

InChI key

ANYSGBYRTLOUPO-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
Sigma Aldrich Fine Chemicals Biosciences Lithium 2,2,6,6-tetramethylpiperidide 97% | 38227-87-1 | MFCD00015910 | 10G
-- ₹ 26,202.75
Lithium 2,2,6,6-tetramethylpiperidide
-- ₹ 15,858.63 - ₹ 21,217.00

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Description

  • Application: Lithium 2,2,6,6-tetramethylpiperidide is a strong base and can be used:For the synthesis of enamines from terminal epoxides through trans-α-lithiated epoxide as an intermediate.[1]For ortholithiation of arenes such as 1,3-bis(trifluoromethyl)benzene, 4,4-dimethyl-2-phenyl-2-oxazoline, 1,4-bis(trifluoromethyl)benzene and 1,3-dimethoxybenzene.[2]In combination with Lewis donor ligand, N,N,N′,N′-tetramethylethylenediamine (TMEDA) for deprotonative metalation of methoxy-substituted arenes.{21]

SAFETY INFORMATION

Pictograms

GHS02,GHS05

Signal Word

Danger

Hazard Statements

H261,H314

Precautionary Statements

P231 + P232 - P280 - P305 + P351 + P338 - P310 - P422

Hazard Classifications

Skin Corr. 1B - Water-react 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable