80631

Sodium bis(trimethylsilyl)amide solution

40% in THF

Manufacturer: Sigma Aldrich

CAS Number: 1070-89-9

Synonym(S): HMN-Na Sol, NaHMDS solution, Hexamethyldisilazane sodium salt solution

Select a Size

Pack Size SKU Availability Price
500 ML 80631-500-ML In Stock ₹ 16,356.58

80631 - 500 ML

₹ 16,356.58

In Stock

Quantity

1

Base Price: ₹ 16,356.58

GST (18%): ₹ 2,944.184

Total Price: ₹ 19,300.764

form

liquid

Quality Level

200

concentration

40% in THF

SMILES string

C[Si](C)(C)N([Na])[Si](C)(C)C

InChI

1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key

WRIKHQLVHPKCJU-UHFFFAOYSA-N

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Description

  • Application: Sodium bis(trimethylsilyl)amide, also known as NaHMDS, is a metal dialkylamide reagent that combines both high basicity and nucleophilicity.[1] It is a general reagent used for the enolization of carbonyl compounds.[2]It can be used to prepare phosphonium ylides in Wittig reaction.[3]NaHMDS solution can also be used as a source of nitrogen in aminomethylation[4] and in the synthesis of primary amines from the corresponding alkyl halides.[5]
  • Other Notes: prices for bulk quantities on request

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H314,H335,H336,H351

Precautionary Statements

P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 2

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves